The optimization of the factors affecting the efficiency of Electro-activation of foam concrete mixes is carried out. For this purpose was applied mathematical planning experiment. As varied factors adopted grain size of sand grains, the value of the applied voltage and the duration of treatment. The mathematical models for strength, high density and structural quality are obtained.
Keywords: Variable electric field, foam-concrete mix, coefficient of structural quality,
The problem of temperature stresses in revetments of concrete plates taking in the account various conditions of temperature impact is considered. Contact conditions for various friction coefficient are considered. The simulation is made using finite element method in Ansys © software. The examples of exact simulations for stress fields are given for different parameters of problem
Keywords: temperature stresses, concrete plate, finite element method
The nano-catalyst ceria (CeO2), activated by Pt nanoparticles, is known for being prospective and efficient material widely used in catalysis, fuel elements, and sensors. One of the most up-to-date methods of catalysts' reasearch is X-ray absorption spectroscopy (XAS) that is sensitive to the chemical state of catalyst's active centers [1,2]. Using XAS in the fluorescense detection mode at CeL1 line with high precision we studied electronic structure of Pt-activated nanoparticles of ceria at various redox conditions. In order to detect partial X-ray fluorescence yield the emission line CeLγ3 was used, which allowed us to increase spectral resolution. We researched local atomic and electronic structure of the materials under study. Oxygen vacansies were found to appear on the nanoparticles surface of ceria at 5% CO He atmosphere. Theoretical modeling of the obtained spectra at CeL1-edge demonstrated good agreement with experiment.
Keywords: X-ray absorption spectroscopy, HERFD, XAS, Ce-based catalysts, oxygen vacansies
The return coefficient task of determination of properties of a construction design by means of the device of neural networks is considered. As model the neural network in the form of a polutorasloyny predictor with possibility of iterative accumulation of volume is taken. Each subsequent step connected with addition of a new stream of neurons, is carried out only after training of the previous stream. Coefficients of synoptic communications pay off with the help of procedure of the return distribution from a condition of a minimum of function of an assessment. Algorithms of the solution of direct and return problems of multidimensional approximation are developed.
Keywords: neural network, approximation, synoptic communications, return distribution, construction designs
The problem of stress concentration near step junction of sections in constructional elements and machine elements has been solved in this article by means of one singular integral equation. The formula for determination of stress concentration factor depending on fillet radius has been submitted.
Keywords: Step plate, singular integral equation, conjugation line, stress concentration factor
This paper studies the dependence of the ratio of prismatic strength (Rb) from cube strength (R) for high-strength concrete of classes B70 ... B110. Experiments were carried on the concrete cubes with an edge of 150 mm and prisms with a base 150x150 mm and a height 600 mm. The tendency to reduce the ratio Rb / R with increasing strength of the concrete is founded. A new relationship Rb = f (R) is offered
Keywords: high-strength concrete, physical experiment, prismatic strength, cube strength, the coefficient of the prismatic strength
In the field of the Museum exposition design in Russia and abroad considerable experience has accumulated. However currently we can state the absence of a comprehensive approach to create a coherent exposition system Exhibition – exhibition space. In this scientific article we formulated the concept of Space-graphic element. We have identified the structure, types and variants of use of space-graphic elements, as a special category of exposition tools in exhibition spaces. We have identified the main technical and compositional principles of space-graphic elements design. The use of those principles will allow organizing a coherent unity system Exposition – exhibition space. Concept of space-graphic elements is useful in the development of Museum and exposition activity.
Keywords: Space-graphic element, Museum-exhibition space, exhibition, principles of design, modularity, transformation, interactivity, integrity, structure, consistency
The paper proposes a new relationship for the analytical description of the diagram «b–b» for high-strength concrete of classes C55/67 ... C90/105. The formula developed on the basis of the accepted in EU relation of Sargin and agrees well with the experimental data. A new relation of the ultimate relative deformation of concrete from the strength is developed
Keywords: high-strength concrete, physical experiment, state diagram of concrete, the stress-strain dependence in concrete, the ultimate relative deformation of concrete
We consider the relevance, peculiarities and the main stages of composite developments in the technology of production of finishing materials based on glass and ceramics. The description of technology of production of universal fragments, making the block-transformer. As basic materials for the development of applied chamotte ceramics and glass sheet.
Keywords: composite development, design, manufacturing technology, unit transformer, fireclay, glass
The problem of formation of assortment of wood plants for the South-West of Rostov region. Proposed main and additional assortment of wood plants, including 159 species. In ассотимент included the most sustainable and eco-efficient exotic plants. The assortment includes species not damage the disease of family Betulaceae, toxic and invasive species (Amfora fruticosa, Ailanthus altissima, etc.).
Keywords: green building, assortment of woody plants, Rostov region, introduction
The article represents the description of the construction of increment borer, its present modifications and additional devices. On the basis of the conducted survey the authors of the article defined the ways for improvement of the borer. Suggested technical solutions are at the stage of patenting
Keywords: Increment borer, preparatory works of forest logging, tree age, forest inventory, core.
Alzheimer's disease is an incurable illness. It affects about half a million people in Russia, and due to the general trend towards aging of the population the number of Alzheimer's disease cases will steadily increase. Insoluble deposits of amyloid beta in the brain tissue (amyloid plaques) are the major morphological characteristic of Alzheimer's disease. It has been found that the increased concentration of copper in amyloid plaques results in copper ions bound to the protein. It is the presence of copper in the binding site triggers of the formation of amyloid plaques. Therefore, the study of the binding site in amyloid beta is of great scientific interest. The local atomic structure of the Cu(I) copper ion binding site in the amyloid beta peptide has been studied by means of XANES spectroscopy. Several model structures obtained by molecular mechanics and density functional theory (ADF code) have been tested. Theoretical analysis of X-ray absorption spectra based on the finite difference method implemented in FDMNES code was performed. An appropriate model structure of the Cu(I) copper ion binding site in amyloid beta peptide has been found.
Keywords: amyloid beta, binding site, Alzheimer's disease, the method of finite differences, Cu(I)
This paper describes an in-situ experimental technique to study of ceria nanocatalysts by using X-ray absorption near edge spectroscopy XANES. This technique allows us to determine Ce3+ concentration inside ceria nanoparticles in the course of catalytic reaction based on the comparison and divergence minimization of the Ce L3 XANES spectrum of the ceria nanoparticles under catalysts (atmosphere, temperature) with a linear combination of two independent components corresponding to spectra of Ce4+ ion of the CeO2 structure and Ce3+ ion of the theoretical Ce2O3 structure. The calculated weight ratio determines the Ce3 + concentration in the sample during the catalytic reactions.
Keywords: in-situ X-ray absorption spectroscopy, HERFD, XAS, ceria nanoparticles, Ce-based catalysts, Ce3+ concentration
The problem of optimization of thick-walled sphere loaded by internal and external pressures was solved. The essence of the method consists in the variation of the modulus of elasticity. The problem of finding the distribution of the characteristics of material in which the stress state is given, is called the inverse problem. The idea of the inverse method was proposed by academician of RAACS prof. V.I. Andreev. The analytical dependence of modulus of elasticity from the radius at which the calculated stress on the strength theory of Mor is constant throughout the thickness of the shell was found. This shell will be equally stressed. If the strength characteristics of the material do not depend on the modulus of elasticity it will also be equiresistant. By creation of indirect heterogeneity we reduced the maximum tensions in 1.6 times. It was also shown that in the case of a centrally symmetric problem the second theory of strength is a particular case of the strength theory of Mor.
Keywords: thick-walled spherical shell, optimization, strength theory of Mor, uniform strength, equal stress
In article questions rationing in the field of the address of waste are reflected, methods of definition of standards of formation of waste are analysed, their quality standard is carried out
Keywords: waste, the education standard, definition methods, limits on placement, ecological safety