The article presents the results of a study of the rheological properties of cement compositions with a polycarboxylate-based plasticizer and stone flour from carbonate rocks of the Saratov region.

Keywords: cement, rheological matrix, powder-activated concrete, superplasticizer, hyperplasticizer, finely dispersed additive, stone crushing waste, stone flour, water-cement ratio, water-reducing effect

The morphology of the modified Portland cement hydration products was studied transmission electron microscopy. The combined effect of polyvinyl alcohol (PVA) and sucrose on the morphology of hydrosilicates nanoparticles has a synergistic character. he presence of PVA enhances the effect of sucrose. The effect of synergism must be considered in the preparation of multicomponent modifier compositions including PVA

Keywords: "modified cement stone, transmission electron microscopy, the morphology of nanoparticles of hydrosilicates, sucrose, PVA, synergistic effect. "

Long-range building materials with possible complex of desired properties are silicate-natric adhesive-based composites. One of effective ways to increase silicate-natric composites water resistance is using of modifying compounds containing polyad metals ions (Zn2+,Ca2+,Mg2+,Al3+). This paper presents some patterns of silicate-natric composites structuring with ethanoate zinc as a water solution. There are results of X-ray phase analysis of silicate-natric composites sample. X-ray phase analysis (XPA) was held with diffractometer проводился на дифрактометре DXGP-4 using X-ray tube with anode copper (Сu-K излучение). For analyzing XRD patterns date base PCPDFWIN, v. 2.02, 1999, (JCPDS) was used. It is clear that as a result of sodium silicate and ethanoate zinc water solutions interaction in optimal range zinc salt is fully under alkaline hydrolysis. It is also highly likely that this interaction produces supplementary compounding sodium acetate, at the initial stage, and various forms of zinc orthosilicate and hydrooxyde, characterized as insoluble and low-soluble compounds respectively, that promotes water resistance increasing of studied composites, when low-baked (110°С). In terms of researches compounds of various profiles are developed and recommended (heat-isolating, heat-isolating-constructive, constructive) with high functional and operating characteristics).

Keywords: liquid nitric glass, ethanoate zinc, modifying, alkaline hydrolysis, zinc orthosilicate, zinc hydrooxyde, sodium acetate, cushioning parameter, water resistance, silicate-natric composites