In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.
Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT
The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by borohydride methode was studed. It was established that the specific activity of fresh prepared Pt3,7Ni/C catalyst in oxygen electroreduction reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment.
Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis
Results of research of influence of processing operations of Nd:YAG of the laser are presented in article, such as the speed of scanning and power of a laser beam on maximum temperature and the thermodeformed status in structure dye-sensitized solar cell. Dependences a component of a tensor of tension are received at various processing operations by means of numerical experiment. Results of researches showed that in intense the deformed status is depend on temperature gradient more, then on coefficients of linear expansion of structure which in this structure differ slightly.
Keywords: laser technologies, thermodeformed, numerical simulation
The problems of building the architecture and design of the database structure for the storage of the structure of the chemical compounds and their analysis using heuristic algorithms
Proposed the structure of the database that allows you to store information about the structure of chemical compounds with varying degrees of detail. This approach simplifies forming of the structural descriptors used to build models of "structure-property" based on the genetic algorithms.
Keywords: database architecture, chemicals, data mining, heuristics
In this work the algorithm for compression and access to compressed voxel data in process of landscape modelling is proposed, which will significantly decrease memory requirements. This algorithm is designed to ease the development of vast voxel landscapes in computer simulations and games. The experimental studies has shown significant gain of voxel model memory efficiency. The aim of this algorithm is to be able to cooperate with surface extraction tools.
Keywords: compression, RLE, run-length encoding, voxel, landscape, virtual reality, operative memory, data
With the use of pulsed laser deposition and carbothermal synthesis а photosensitive structure on the basis of the Schottky barrier Au/ZnO(nanorods)/ZnO(film)/ZnO(nanorods)/Au was obtained. The parameters of the carbothermal method of synthesis of nanorods ZnO were optimized. Under directly applied bias of 7V current sensitivity of luminous flux for this photodetector is observed in the UV and visible regions of the spectrum, and is 0.14 A/W - for 325 nm and 0.18 A/W - to 405 nm, which means that this structure has the ability of potential applications in various fields for the control of UV radiation (for example, for the monitoring of solar UV radiation, control of UV radiation in air and disinfecting water devices).
Keywords: ZnO nanorods, Schottky barrier, photodetector, photosensitivity
ZnO nanorod arrays have been synthesized on silicon wafers by chemical vapor deposition (CVD) technique with different temperature modes, without metal catalyst. With this method vertically aligned ZnO nanostructures were grown at the quite low temperatures. Modification of the method allowed to place silicon substrates in areas with different ratios of concentrations of the molecules in the vapor phase. Photoluminescence spectroscopy and electron microscopy studies have shown that morphologies and optical properties of nanorods depends on different ratios of concentrations of the molecules in the vapor phase.
Keywords: ZnO nanorods,chemical vapor deposition (CVD), photoluminescence
The arrays of ZnO nanorods were obtained on the sapphire substrates by means of pulsed laser deposition under the high pressure of argon. The conditions of synthesis were optimized, and their influence on the morphology of ZnO nanostructures were revealed. It is shown that the concentration of oxygen vacancies in ZnO nanorods can be changed by regulation of the synthesis temperature from 850 to 915 °. This process can be controlled by the ratio of intensities of the photoluminescence emission in the visible and ultraviolet regions. So, it allows to create nanostructures for UV photodetectors or chemosensors depending on the temperature choice.
Keywords: ZnO nanorods, laser deposition, PLD, photoluminescence
The method of application of fuzzy logic to solve the problem of spatial planning using geographic and information systems is described. The spatial arrangement of objects on the map is used as input factors of the solution, to find which a model of the spatial descriptions of objects using a bitmap representation is constructed. The way of formalizing fuzzy judgments about positional relationship of objects and the system of inference making based on the fuzzy logic methods is developed. An example of using the method described in this article to determine the sanitary protection zone of industrial waste landfill in the territory of the Republic of Bashkortostan is given
Keywords: fuzzy logic, geographic information systems, the problem of territorial planning, disposal of industrial waste, protection zones
At the present time in most countries of the world are being actively developed and introduced intelligent technologies necessary for creation of reliable and effective intellectual energy systems. Intellectualization of distributive electrical grids will move energy system to a new level of automation. Evenly distributed electrical grid of hexagonal type was offered. The principle of creation a grids was described, a typical scheme of universal electrical load unit was proposed. The key advantages of the hexagonal network was reviewed. The estimation of the reduction of the level of losses during electricity transportation was made. The increase of the level of reliability, the factors affecting the probability of faultless work were determined. Evenly distributed grids of hexagonal type will build energy system based on Smart Grid and solve existing problems: lower quality of electricity, the shortcomings of the power reserves, high density of electrical loads and high energy losses. Project implementation should be carried out in stages: from pilot project to implementation in big cities.
Work is executed with financial support of Ministry of education and science of the Russian Federation (state contract №14.516.11.0104 from 14.10.2013).
Keywords: electricity, hexagonal grids, smart grids, distribution grids 10-20 kV, reliability of power supply
The results of research of raw materials of the logs production for timber construction are considered in the article. Length of logs (for 6 meters assortment), diameter of logs (model logs) and shape of butt (an average shape factor of butt) were studied. The model log is a volume of cylinder which is equal to a calculated volume of logs. The theoretical laws of the random variable for these values are found. The Research was conducted at LLC "Biogran" in Petrozavodsk, Republic of Karelia.
Keywords: Woodworking, cylindering, technological line, wood costraction, factors, length of a log, diameter of a log, butt
In the article authors examine specificities of internal components behavior changing in fiber-optical cable under influence of strong variable uniform electromagnetic field. There are some process variations proposed for describing of obtained results.
Keywords: fiber-optical cable, electrothermal degradation, kevlar, conductivity, open fiber-optical cable, partial discharges, water treeing
The article describes peculiarities of modern syntax parser systems and problems originating in text analysis. As a result of comparative analysis the authors propose a unified approach to processing of unstructured texts in Russian and English which combines morphology and syntax processing. The developed syntax analysis system, using verbs’ valency dictionary, samples of minimal structural schemes of sentences and samples of conjunctions, allows choosing predicative structures of sentences in the text, realizing initial semantic analysis due to semantic content of predicate’s actants and building trees of syntactical subordination of sentences. The derived trees hold elements of tree of constitutives and tree of dependences. The proposed samples and rules organization allows resolving some of the problems of modern parsers. And the use of verbs’ valency dictionary allows reducing the number of sentences syntax analysis variants.
Keywords: automatic text processing; syntax parser; morphological analysis; structural text elements
Described a variety of available master data integration methods and techniques. Proposed a method for data enrichment in connected autonomous systems based on applying custom written master data access functions available via global meta catalog.
Keywords: data integration, master data, business processes, enterprise service bus, enterprise application integration
In this work experimentally investigated the possibilities of the new method of obtaining adjustable roughness on metal surfaces electrothermal influence of mobile cathode spots in vacuum arc discharge. Presents the results of processing of various surfaces using this method. Proposed working modes of processing of metal surfaces with the aim to receive as minimum and maximum roughness.
Keywords: roughness of metal surfaces, vacuum arc discharge, cathodic spots