In this article is reviewed the nature of organic hybrid nanocomposites. Promising directions in the field of organic hybrid nanocomposite materials will be methods for the synthesis of multicomponent materials, as well as the type of "net net" and "host-guest". The fundamental problem with the chemistry and physics of nanocomposites is dependent "structure-property". Solving this problem will move from research materials to their purposeful design.

Keywords: nanocomposite sol-gel technology, synthesis, nanoparticles.

At present an important role in solving energy conservation problem is assigned to thermal pumping plants (TPP). Using processes of evaporation and condensation of easily boiling liquid circulating in the system they extract low potential heat from environmental objects and provide heat supply for buildings, constructions, greenhousee and so on. Artificial sources of low potential heat for TPP of different capacity can be, for instance, ventilation air and exhaust gases, circulating and waste water,ground. Energy efficient reasonability of TPP use in the system of water disposal for the town of Novocherkassk in Rostov region is considered. Calculations indicate that there is a technical potential to replace a boiler house operating on expensive gas fuel and emissing into the atmospere more than 850 t of carbon dioxide - greenhouse gas - with ecologically clean TPP, one of which uses heat of waste water and the other - heat of ground.

Keywords: thermal pumping plant, renewable sources, energy conservation, evaporation, condensation, waste water, ground

The method of coding of the geometrical information is offered at the task of executive mechanisms on the basis of use of the set set of spatial primitive things and their orientation in mobile systems of co-ordinates. The method of a designation of geometrical models of mechanisms of robots is offered. One of advantages of the developed method of representation of geometrical models of kinematic chains, possibility of more exact task of a spatial configuration of manipulators by means of use of a considerable quantity of central points and various position of volume primitive things concerning a constructive plane is.

Keywords: Mechanisms of manipulators, geometrical models, virtual modelling of movements of robots

In the article describes the program realization of calculation unit pneumatic measuring system. The program is implemented in the languages ​​of IEC: CFC and ST. Algorithm written with the possibility of future use in systems that differ from described in the article. The developed algorithm allows to measure temperature directly using computing power PLC and get the result in the final form, without any changes on the part of the operator.

Keywords: pneumatics, temperature, airflow, algorithm of temperature measuring, temperature measurement, Codesys, CFC, ST

Simulation and method of classification of technical condition high-voltage the mekhatronics of modules of the movement, allowing by results of control of electrodigit activity and skrednekvadratichesky value of vibrospeed are presented, to refer current state of object to one of classes of diagnoses

Keywords: High-voltage mekhatronics module, fuzzy-model of classification of technical condition, electrodigital activity, vibrospeed

The research of influence of periodical signal discontinuity on spectrum form is considered in the article. The numerical modeling of the system of discontinuous signals is performed. The spectrum of the system built from time discreet sampling is analyzed. The plots of the sample correlation coefficient between spectrums of continuous and discontinues signals are shown in the article. The research is needed for the development of digital measuring system for quartz plates frequency detecting.

Keywords: amplitude signal spectrum, discontinuous signal, quartz plates

The atomic structure of bimetallic nanoparticles of Pt-Ag composition, which are the part of metal-carbon electro-catalysts PtAg/C, is studied by means of EXAFS spectroscopy using the suggested technique. These materials have been prepared by methods of consistent and simultaneous deposition of Ag and Pt atoms from aqueous ethylene glycol solutions of their salts with subsequent acid treatment. The values ​​of the structural parameters of the near environment of platinum atoms are determined. The nature of the distribution of components in nanoparticles is established. Cluster models of nanoparticles are constructed. The fraction of Pt atoms in the working shell and its dependance on preparation methods in each case are determined.

Keywords: Metal-carbon electrocatalysts, bimetallic nanoparticles, Catalysis, Platinum, X-ray absorption spectroscopy, atomic structure

The quantum and chemical simulation (HF/MP2, cc-pVDZ basis) of diphenyl-2,2',4,4'-tetraamine (DPTA) molecule properties allows to determine the its thin film pyroelectric properties since hydrogen bonds between molecules in the film are weaker than intramolecular bonds. The study of a DPTA photosensitive pyroelectric film microstructure enables one to assume that the dipole moment of the needle-shaped crystallines densely stacked and extended along a film surface is aligned perpendicularly to the surface. The possibility of the reproduced control for DPTA properties may be used when producing the most effective pyroelectric film for photodetectors in infrared wavelength range.

Keywords: Diphenyl-2,2',4,4'-tetraamine, quantum chemical simulation, pyroelectric material, thin-film structure

The basic virtue of the sowing apparatus of an overpressure is possibility of conducting of sowing on the big speeds and with high uniformity of dispensing of seeds. But the processes occurring in the sowing apparatus of an overpressure at dispensing of seeds, are insufficiently studied. In the article one of stages of process of dispensing by the overpressure sowing apparatus - transportation of a unit seed by dosing elements of a seed disc is observed. The forces acting on a seed in the course of transportation with a dosing element of a seed disc are defined. The gravity, centrifugal force, force of air drag and pressure force of air refers to to them. The scheme of forces is presented. As a consequence of theoretical research dependence of magnitude of an overpressure in the seed vessel from key parameters of work of the sowing apparatus of an overpressure has been defined. Graphs of theoretical dependence of pressure in the seed vessel from diameter of holes and a seed disc angle of rotation are built. The analysis of the gained results allows to draw following conclusions. The increase in diameter of holes of dosing elements of a seed disc leads to considerable decrease of the pressure necessary for transportation of a seed. At increase in an angular velocity of a seed disc pressure necessary for the secured transportation of a seed is augmented. The increase in an angle of rotation of a seed disc puts insignificant agency on pressure in the apparatus seed vessel.

Keywords: seeds, transportation, dispensing, forces, an overpressure, a dosing element, a nominal diameter, dependence.

The article shows the necessity of the research effort results state registration in the form of intellectual property objects – databases and software products. The Petrozavodsk State University’s experience in this field is shown

Keywords: Database, intellectual property, software products, intellectual activity result

This paper offers an improvement for machine vision based tracking algorithm using NARX neural network. This is achieved by predicting the next position of a mobile agent based on previous movement described by time-series functions. The algorithm remains passive and does not interfere with the quadrotr flight path until detection of multiple agent-candidates, when the tracking algorithm is not able to identify or locate the assigned agent. Meanwhile the NARX training set are updated in parallel with each successful tracking cycle. This process is done to eliminate the overfitting problem of BPTT training.

Keywords: NARX, quadrotor, agent tracking, local minimum problem, machine vision

On the basis of the conducted questionnaire survey of the inhabitants of the Kirov region identified determinants of consumption individuals of cultivated mushrooms. Built a factor model of the market of cultivated mushrooms Kirov region

Keywords: Market of cultivated mushrooms, discriminant analysis, factor analysis

The paper studies the possibility of interaction of acrylamide with aliphatic di-, tri-, tetra- and pentaamines using quantum chemical ab initio modeling. The interest to the preparation of these compounds can only increase since they may serve as feedstock for the production of other useful materials which may find adequate application. The choice of reaction conditions depends on the thermodynamic principles of the process, and for that reason, the paper determines thermodynamic parameters and the logarithms of the equilibrium constants of acrylamide reaction with aliphatic amines in ratio of 1:1 and 2:1 in the gas phase by quantum-chemical method based on density functional theory using a hybrid exchange-correlation of B3LYP functions in the basis of 3 -21G* within 273 ÷ 450 K temperature range and pressure of 0.1 MPa. These calculations served as a base for defining the conditions that must be followed when developing the technology for these compounds, and it was shown that the reaction of their synthesis with high probability of acrylamide - amine reactants ratio of 2:1 should be conducted under relatively mild conditions. Theoretical calculations comply with the experiment, because the interaction of acrylamide with amines at various ratios of reagents and temperatures within 325 ÷ 330 K leads predominantly to the transformation at acrylamide-amine 2:1 reagent ratio, as evidenced by the number of reactive reagents, and frequency analysis of FT-IR, NMR 1H and 13C spectra.  Thus, the possibilities of mathematical modeling allow determining the highest probability of spontaneity for a particular reaction, using the method of computer simulation by changing the process temperature (within the model) without performing any technological experiments.
       

Keywords: Acrylamide, aliphatic amines, ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepenta-amine, thermodynamic parameters, Gibbs free energy, isobaric-isothermal potential, equilibrium constant.

Results of development of new high-performance technology of hardening and balancing of abrasive circles due to drawing detonation ceramic coverings are presented. The method of calculation of rational thickness of the ceramic covering creating in volume of a circle favorable residual squeezing tension is given. The way of balancing of abrasive circles at the expense of the uneven thickness of the covering put on their lateral surfaces is shown. Results of researches of influence of the sizes of abrasive circles at a size of residual tension are presented.

Keywords: Abrasive circle, hardening of an abrasive circle, detonation covering, balancing, internal tension

In article the main approaches to creation of information structure of a post of diagnosing of the car, providing an optimum combination of the logical conditions solved automatically and non-automatic, raktsionalny distribution of information on types and form representations when developing a method and means of diagnosing are stated

Keywords: diagnosing, post, information structure, model