The properties of the water-soluble high-modulus silicate systems: based on alkali metal polysilicates called liquid glass and chain their transformation from lower to higher oligomers, with the subsequent formation of colloidal solutions - silica sol. The methods of preparation, properties and applications of water-soluble high-modulus silicate systems. The possibilities of their use as a binder and modifying agents for various nanostructured composite materials. The examples of promising areas of application of liquid glass and high modulus of aqueous solutions of silicates in construction and industry. In particular show the possibility of using liquid glass and aqueous solutions of silicates in the production of nanostructured silicate polymer. In space engineering for manufacturing water-destructed mandrels used in the manufacture of solid rocket motor casings and pressure vessels 'cocoon' of composite materials by winding. The application of the inorganic sol to obtain a nanocomposite ceramics and monolithic blocks of silicon oxide, which can be used in various fields of modern technology. The possibility of using silica sol as a binder for refractory ultra-lightweight shielding materials used to protect equipment from high impacts. The directions of development of the production of new acid-resistant materials and linings for protection of chemical equipment, parts and components operating in corrosive environments.
Keywords: Keywords: water glass, silicate polymer concrete, additives, silicates organic bases tetrafurfuriloksisilan, furfural alcohol, nanostructure composite materials, water-soluble silicates, silica sol, sol-gel transition, cured xerogel water-destructed mandr
In the article obtaining of cathodic coating MnO2 on condenser porous tantalum anode was researched. It was ascertained that formation of crystalline defects from hydrated MnO2 on MnO2 coating obtaining by known technology is possible. Such formations disturb tantalum capacitor cathode integrity. To determine the reasons of the crystal defects formation conveyed simultaneous thermal analysis of Mn(NO3)2x4H2O and Mn(NO3)2x6H2O with an analysis of the flue gases by FTIR spectroscopy. Based on the analysis results a mechanism of manganese nitrate thermolysis was suggested and the cause of the crystal defects on the surface after the coating of manganese dioxide removed from the furnace was ascertained. It was established that the thermolysis process is followed by the formation of such manganese nitrate intermediates as manganese hydroxynitrate, manganese oxyhydroxide and its further oxidation to manganese dioxide. Because of secondary processes leaking on the MnO2 cover manganese oxyhydroxide residual can react with water vapor and oxygen, that leads to the formation of crystalline defects. Such phenomenon has a negative impact on the chemical composition and integrity of the coating on the surface of the porous MnO2 tantalum capacitor anode. Also it has been found experimentally that manganese hydroxynitrate is formed from manganese nitrate in the form of microtubules on the porous tantalum vehicle surface.
Keywords: manganese dioxide, coating, manganese nitrate, thermolysis, crystalline defects, microtubules
In article consider the development of modeling spatial spread of epidemics to improve the quality and accuracy of anti-epidemic situation using a combination of simulation model based on stochastic model of compartmental and cellular automaton. The epidemic is spatially distributed dynamical system to describe the spatial- temporal behavior of the application of models which class of cellular automata. Cellular automata are discrete dynamical systems, which is a collection of identical cells, the same way interconnected. All cells form, the so-called lattice cellular automaton. Lattice can be of different types, differing both in dimension and shape of cells. Each cell is a finite state machine whose states are determined by the states of neighboring cells. Cells can be placed on a one-dimensional line, plane or in a multidimensional space
Keywords: Cellular automata, simulation modeling, mathematical model, epidemic diseases, model of cholera, dynamical system, Anylogic
The solid solution of LiMn1/3Cr1/3Fe1/3O2 with the structure of α-NaFeO2 isostructural with the widely used LiCoO2 has been synthesized and investigated as a cathode material. Rated voltage of LiMn1/3Cr1/3Fe1/3O2 relative to the lithium is 4 V. The possibility of charging − discharging the material to a specific capacity of 220-250 mAh/g at currents of C/15-C/50 without phase transformations has been experimentally demonstrated.
Keywords: lithium-ion batteries, cathode materials, Delafosse, solid solution, X-ray structural analysis, electrochemical properties
Based on the analysis of works of finnish experts shows that learning russian language with learning the finnish language as a foreign supports the development of bilingual identity and language readiness of students.
Keywords: russian, finnish, teaching.
The new way of the organization of multistage time-frequency signal localization subsystems is considered. The investigations are constrained by finite impulse response class of digital circuits.
The example illustrated the principle of agreement between pyramidal structure, formed of multistage including of any simple analysis/synthesis subsystem, and channel characteristics. This principle makes possible more precise localization of the input signal in separate frequency bands. The adaptive structure formation of the time/frequency transformation allows increasing of parameters characterizing the effectiveness of the subband adaptive filters (SAF).
Application of the method of flexible time/frequency localization structure formation in the adaptive filtering problems allows significantly decreasing of processor loading by real-time realization of SAF.
The other important advantage of the flexible SAF formation based on the least-mean-square algorithm lies in reducing of the adaptation period for the adaptive system.
Keywords: adaptation, filter, multirate, signal, time/frequency
This article discusses the emergence Chaharbag in different places of the world and the role Chaharbag in development of landscape architecture and urban spaces of identity, as well as its influence on other arts including painting and carpet. Chahar Bagh is a special style layout, which is used in the Persian garden. Rectangular in plan shared garden paths or channels with flowing water into four smaller parts. In Persian, "Chahar" means "four" and "Bag" is translated as "garden".
Keywords: Chaharbagh, garden, Persian garden and landscape.
Maximum power pointtracking algorithms are widely used in the solar converters in order to obtain maximum power from the solar array. The article provides a brief description of the work of these algorithms, description of the method of testing based on mathematical modeling using Matlab, Simulink and SimScape packages. The results of modeling and comparative analysis of the studied algorithms, its strengths and weaknesses revealed.
Keywords: maximum power point, maximum power point tracker, photovoltaic, buck converter, comparative study of algorithms, perturb and observe method, constant voltage method, constant current method, icremental conductance method
Fe-doped AlN nanorods were studied by means of x-ray absorption spectroscopy above the Fe K- and L2,3- edges. Theoretical simulations of the x-ray absorption spectra show that Fe atoms mainly substitute Al. A minor fraction of Fe interstitials or Fe-Al-N ternary alloy can be identified as well. Bader’s AIM analysis predicts that neutral substitutional FeAl defect is in 2+ charge state, though Al in pure AlN is in 3+ charge state. Fe L2,3 absorption spectra and photoluminescence data indicate the coexistence of Fe2+/Fe3+ in AlN:Fe nanorods so different charge states of substitutional FeAl should co-exist.
Keywords: diversification of management, production diversification, financial and economic purposes of a diversification, technological purposes of ensuring flexibility of production
This article reviews systems of respiratory activity registration in relation to sports medicine. Attention is devoted to the use of miniature accelerometers that record the movement of the chest, as the optimal method for the diagnosis of the respiratory parameters. Other methods are based on piezo-resistive sensors, pressure and airflow sensors, and airways resistance sensors. The authors' developed device based on three-axis accelerometer is proposed. It recognizes episodes of apnea with sufficient accuracy for long-term monitoring. The algorithm of the accelerometer data processing is described. In order to minimize noise impact on the useful signal it is necessary to transform the three-dimensional cloud of accelerometer data into a flat sector. Then the relation of gravity vector deviation angle and the nominal position in time is determined. This presented device due to its ability to transmit data via Bluetooth technology, after appropriate software development for mobile phone and the receiving terminal of medical professional, will be able to organize a simple ergonomic long-term remote monitoring of respiratory activity.
Keywords: systems of respiratory activity registration, long-term remote monitoring, three-axis accelerometer
In article the structure, functional architecture and mathematical model of the system intended for automated management by information procedures in the automated information system are considered. The offered model is based on monitoring of initial and flowing conditions of the information streams subjected recomposition on the basis of operating markers by the serving router. A system kernel is the Server of configurations supporting discrete disciplines of management by service.
Keywords: information service, priority management, an information stream
In this paper we study of the local atomic and electronic structure of nanostructured condensed material for rechargeable current sources on the basis of 15mas.%V2O5/Fe/LiF nanocomposite within charge-discharge cycle. Principle component analysis (PCA) of the series of Fe K-edge spectra collected during 1 st charge showing the concentrations of the components Fe, FeF2 and V[FeV]O4. We found the changes in the V oxidation state from the analysis of the experimental Fe K- and V K- XANES spectra. Total and partial density of states of components are presented.
Keywords: nanostructured materials for rechargeable current sources, dynamics of local atomic and electronic structures, XANES, DFT
The catalytic activity of Pt/C and PtxNi/C electrocatalysts prepared by borohydride methode was studed. It was established that the specific activity of fresh prepared Pt3,7Ni/C catalyst in oxygen electroreduction reaction is higher in compare with Pt/C material. After treatment of Pt3,7Ni/C material in the hot acid nickel in the surface layers of nanoparticles was dissolved and the composition of nanoparticles was changed to Pt5,6Ni. The electrochemical surface area of the Pt5,6Ni catalyst and specific activity was slightly decreased after corrosion treatment.
Keywords: platinum electrocatalysts, corrosion stability of the nanoparticles, fuel cells, X-ray diffraction, borohydride synthesis
The problems of building the architecture and design of the database structure for the storage of the structure of the chemical compounds and their analysis using heuristic algorithms
Proposed the structure of the database that allows you to store information about the structure of chemical compounds with varying degrees of detail. This approach simplifies forming of the structural descriptors used to build models of "structure-property" based on the genetic algorithms.
Keywords: database architecture, chemicals, data mining, heuristics
Considered the proposed approach to the allocation of resource flows. The approach developed on the basis of the method of bee colonies. Experimentally determined the dependence of the error of the algorithm of the problem dimension. Shows the dependence of the distribution of resources from a number of iterations, and the power of the swarm, and dynamics approximation of the distribution to the optimum.
Keywords: optimization, distribution, collective adaptation, evolution, the error of the algorithm