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  • Synthesis and electrochemical characteristics of the new composite cathode material of LiMn2O4@LiCoO2 for lithium-ion battery

    The composite cathode material of the core@shell type with the LiMn2O4@LiCoO2 formula of has been successfully synthesized using the solid-state reactions in several stages. Its structure has been studied by means of X-ray diffraction, scanning and transmission electron microscopy and vibrational infrared spectroscopy. Electrochemical investigation in two-electrode cell has been showed improvement of characteristics of the synthesized cathode material than the constituent components. The specific power of LiMn2O4@LiCoO2 is 650 mWh/g, against 450 and 500 mWh/g for LiCoO2 and LiMn2O4, respectively.

    Keywords: lithium-ion batteries, cathode materials, Delafosse, X-ray structural analysis, electron microscopy, electrochemical properties

  • Method for railway car numbers block recognition based on committee neuroimmune classification

    This paper presents a new neuroimmune-based method for block recognition of railway rolling stock inventory numbers. The advantage of such approach is  classification without using of negative samples. Developed technique combines segmentation and classification that allows to achieve higher noise robustness, segmentation possibility of fuzzy combined digits which have different fonts and typeface, and invariance of existing numbers to scale changes. Proposed method allows to constantly increase the training set for the improvement in classification accuracy by new committee classifiers statistics due to the data reduction property achieved by using the immune clustering mechanism. Research results were implemented in the software system of automatic recognition of cars numbers (ARNV), which is operated on the JSC Russian Railways.

    Keywords: Method for letters block recognition, the committee neuroimmune classification model, identification, automatic recognition car number, duplicate number

  • Display of the orthogonal projection of a four-dimensional hypersurface


    Problem research of display the orthogonal projection of four dimensional hypersurface defined by the equation in an implicit form one and two hyperplane. To communicate and bypass hypersurface Discriminants assumes that the hypersurface of the two-parameter family of two-dimensional display received surfaces in five-dimensional space. The analysis of kriminant four dimensional hypersurface orthogonal projection onto the coordinate hyperplane in two coordinate axes. The intersection of three dimensional hypersurfaces axiom (kriminant) defines a two-dimensional surface that is the envelope of the two-parameter family of two-dimensional surfaces. Are the necessary and sufficient conditions of existence of this envelope.
    The results obtained are used to study the Discriminants four-dimensional hypersurface, the display of two-parameter family of spheres in a five-dimensional space.  

    Keywords: a family of surfaces, hypersurface, envelope, the display features, а discriminant.

  • Adaptive agent's behavior: the effects of actions and acceptor efferent synthesis

    Peculiarities mechanisms predict and evaluate the results of actions of an intelligent agent. Building and planning procedures and correction strategy and tactics based on the behavior of a cybernetic circuit functional systems. This scheme is a concept of an intelligent agent architecture.

    Keywords: Intelligent agent, adaptive behavior, the model achieve the goal, the efferent mechanism synthesis

  • Liquid glass and aqueous solutions of silicates, as a promising basis for technological processes of new nanocomposite materials

    The properties of the water-soluble high-modulus silicate systems: based on alkali metal polysilicates called liquid glass and chain their transformation from lower to higher oligomers, with the subsequent formation of colloidal solutions - silica sol. The methods of preparation, properties and applications of water-soluble high-modulus silicate systems. The possibilities of their use as a binder and modifying agents for various nanostructured composite materials. The examples of promising areas of application of liquid glass and high modulus of aqueous solutions of silicates in construction and industry. In particular show the possibility of using liquid glass and aqueous solutions of silicates in the production of nanostructured silicate polymer. In space engineering for manufacturing water-destructed mandrels used in the manufacture of solid rocket motor casings and pressure vessels 'cocoon' of composite materials by winding. The application of the inorganic sol to obtain a nanocomposite ceramics and monolithic blocks of silicon oxide, which can be used in various fields of modern technology. The possibility of using silica sol as a binder for refractory ultra-lightweight shielding materials used to protect equipment from high impacts. The directions of development of the production of new acid-resistant materials and linings for protection of chemical equipment, parts and components operating in corrosive environments.

    Keywords: Keywords: water glass, silicate polymer concrete, additives, silicates organic bases tetrafurfuriloksisilan, furfural alcohol, nanostructure composite materials, water-soluble silicates, silica sol, sol-gel transition, cured xerogel water-destructed mandr

  • Simulation of the process of optimal placement of goods in stock self-service by evolutionary search algorithms

    The paper contains a description of a new method for automatic generation of maps of goods placement. Map of goods placement created by the author's search algorithm. The algorithm is based on ideas of evolutionary search. The proposed algorithm works with a population of constant size, allows not use complex search methods and for a reasonable time find a solution close to the optimum.

    Keywords: simulation, evolutionary computation, multicriteria optimization, genetic algorithms

  • Determining the most efficient method and the availability of the field condensate pipeline diagnostics in the absence of the main product being pumped

    Development of the field condensate pipeline diagnostics scenario in the absence of the main product being pumped because of shutting down production process. Different diagnostics scenarios modeled by author and the most efficient method choosing were considered in this article.

    Keywords: Pipeline diagnostics, operation regime, scenario, nitrogen, diagnostic options

  • Synthesis and electrochemical properties of LiMn1/3Cr1/3Fe1/3O2 solid solution with the structure of α-NaFeO2

    The solid solution of  LiMn1/3Cr1/3Fe1/3O2 with the structure of α-NaFeO2  isostructural with the widely used LiCoO2  has been synthesized and investigated as a cathode material. Rated voltage of LiMn1/3Cr1/3Fe1/3O2  relative to the lithium is 4 V.  The possibility of charging − discharging the material to a specific capacity of 220-250 mAh/g at currents of C/15-C/50 without phase transformations has been experimentally demonstrated. 

    Keywords: lithium-ion batteries, cathode materials, Delafosse, solid solution, X-ray structural analysis, electrochemical properties

  • Stability analysis of deep loosening slopes.

    The results of calculations on the stability of slope lands treated in a new way. Device intrasoil walls combined with loosened intervals allows prevent subsurface runoff water, which reduces surface erosion slopes, improves the fertility of farmland returns a highly eroded areas in turn, eliminates the wetlands at the foot of the slopes. Established that the stability of the treated soil layer on the slope ample.

    Keywords: stability of sloping land, subsurface walls, soil subsurface runoff, soil erosion, wetlands, deep tillage, moisture saturation slope.

  • Some aspects of finnish language teaching russian as a foreign language and how family in Finland

    Based on the analysis of works of finnish experts shows that learning russian language with learning the finnish language as a foreign supports the development of bilingual identity and language readiness of students. 

    Keywords: russian, finnish, teaching.

  • Problem of determining the residual resource of technical condition of low pressure closed spillways waterworks

    Currently, more than 80% of water conveyance structures worked much the normative life. At the same time there is a simultaneous increase in the load on the aging waterworks, in the absence of the necessary skilled personnel and technical repair base will inevitably lead to an increase in the number of accidents due to operational reasons. Identification of factors that influence the condition of the facilities at the intersections , the search for methods of calculation and control of non-destructive methods to evaluate their work , life extension , etc. is of paramount importance at this stage. Residual life for the safe operation of water conveyance structures determined on the basis of system analysis with the development of the block diagram of a dynamic system having a number of subsystems. The main property that determines the life of the system , is the reliability of its elements , ie reliability and trouble-free operation for a certain period of operation. Dependability and reliability of the system as a whole is determined by the condition that each element of the system can be in one of two states - serviceable or failure.

    Keywords: water-conducting structures, low head hydro closed spillways, modeling, technical condition, residual life.

  • Chaharbagh is the Initial example of the great gardens of human civilization

    This article discusses the emergence Chaharbag in different places of the world and the role Chaharbag in development of landscape architecture and urban spaces of identity, as well as its influence on other arts including painting and carpet. Chahar Bagh is a special style layout, which is used in the Persian garden. Rectangular in plan shared garden paths or channels with flowing water into four smaller parts. In Persian, "Chahar" means "four" and "Bag" is translated as "garden".

    Keywords: Chaharbagh, garden, Persian garden and landscape.

  • Features of the spinel phases formation in system NiO – CoO – CuO – Cr2O3

    The combination of the unique, abnormal properties shown by oxidic systems with structure of spinel on the basis of transitional elements chromites draws attention of researchers for many years. Some systems on the basis of transitional elements chromites (for example, nickel and copper chromites) have critical elements (multicritical points, lines of phase transitions of the second sort, etc.) on the phase chart. Near these elements of the phase chart materials possess unique chemical and physical properties. Therefore development methods of receiving and research of phase forming and properties in NIO-CoO-CuO-Cr2O3 system represent fundamental and practical interest for chemistry and technology of inorganic substances. In this work processes of spinel structure formation in system 0,6 NiCr2O4 – 0,2 CoCr2O4 – 0,2 CuCr2O4 from crystal chemistry positions are considered. Formation of two solid solutions on the basis of nickel (II) chromite – with structure of cubic spinel and with tetragonal distorted structure is established. The influence of cooperative Yahn-Teller effect on processes of a spinel forming and on stabilizing impact of chloride of potassium on process of education of  two spinel solid solutions is suggested. Influence of a power factor of cation stabilization in knots of a crystal lattice as one of the important factor in reaction of spinel structure formation is considered.

    Keywords: spinels, chromites of transitional elements, Jahn-Teller effect

  • Using of large-scale waste phosphogypsum to reduce emissions of SO2-containing coal power plant

    Possibility of using of a phosphate for receiving lime which can be used further as a sorbent of oxides of sulfur in coppers with technology of the circulating boiling layer, applied on coal thermal power plants is considered.

    Keywords: enterprises of power industry, phosphogypsum, with CFB boilers - circulating boiling layer, pollution of the atmosphere, sulphur dioxide, secondary resources, sulfuric acid

  • Evaluation of communicative competence of students based on polytomous model

    The article explains the possibility of using polytomous models to assess personality traits that affect  on communicative competencies of students.
    Input data obtained using a questionnaire V.V. Boyko  " Communicative tolerance " have been used for calculating the characteristics of survey participants and  indicators of the test.  

    Keywords: level of student latent variables, polytomous model indicator, a diagnostic test.