The article discusses the possible causes of pollution of Taganrog Bay of the Azov Sea with oil products for the period 2008-2013. The key factors of pollution were highlighted. Effects of navigation for cotion was evaluated by navigation intensity. Effect of wastewater was evaluated by the number of oil products which fall from municipal drains and wastewater from industrial plants. The data processing of the federal statistical reporting on the influence of the main contamination factors was carried out.
Keywords: oil products, water pollution, average annual concentrations
The method of laser therapy is based on synchronization of phases of inflow (anacrotism) and outflow of blood (catacrotism) in the field of the pathological center with phases of a being narrowed and extending laser spot on a projection of this pathological center. It is supposed that being narrowed on a projection of the pathological center the spot of laser light stimulates blood inflow to the spot center, and the extending spot of a laser beam – activates blood outflow in the direction from the spot center to its periphery. The developed technique of the automated correction of hemodynamic frustration consists in pilot signal formation (in charge of the power and laser positioning) for the laser machine on the basis of a difference between a reference rheogram and a rheogram of the patient (a body site) in real time.The offered technique has to allow to use more efficiently methods of laser therapy at treatment of violations of a blood-groove. The technique is calculated on the basis of numerical experiment by means of methods of mathematical model operation.In the real experiment the question of synchronization of the reference and measured signal is considered solved though this task represents a subject of separate researches.The received pilot signal can be in real time transformed to the current signal operating positioning and laser power.The method gives the chance of an operating control of a condition of the patient and blood-groove diagnostics to, in time and after a session of laser therapy. Development provides possibility of adaptive individual correction and optimization of parameters of influence during a session and a course of treatment.
Keywords: laser, therapy, technique, rheogram, diagnostics, blood-groove, management, signal
Nonstoichiometric tungsten oxides WO3–x and oxide alkaline tungsten bronzes have been studied because of their potential applications in electrochromic devices such as solar panel arrays and “smart windows”. Different phases of
WO3–x have been considered. In this part we present results of our research which clearly show that all Magneli phases of tungsten oxides WOx (namely W40O118, W20O58, W5O14, W18O49, W8O23, W3O8) and oxide tungsten bronzes MxMyWO3 at M-Li, Na, K, Rb, Cs. They are characterized by metal – like properties. Their band structures display an energy gap in the valence band just below the Fermi level.
We present results of our electrochemical synthesis of tungsten oxide bronzes in ionic melts of the polytungsten salts. Among the new state – of – the art methods for their manufacture, electrochemical synthesis in ionic melts, which makes considerably better use of existing technologies, is highly productive, based on the discharge of oxyanions of the polytungstates.
Keywords: oxide alkali bronzes, alkaline tungsten bronzes, tungsten, molybdenum, nonstoichiometry, tungsten oxides, electroconductivity, electrochromism
The aim of this work was to conduct monitoring and make a regression model of the microbiological air pollution in Volgograd near highways. The work carried out monitoring of microbial air pollution in the residential district of Volgograd near two major highways - first and second longitudinal lines. On the first phase of research the microbial monitoring of air pollution in the residential district of Volgograd was conducted, depending on the proximity to the highway. Number of microbial cells (MC) was evaluated by sedimentation. The assumption is made about the nature of the regression relationship between microbial air pollution and the distance from the highway. Approximating functions and regression coefficients are constructed for the first portion of the longitudinal line at different levels of traffic road. Function is obtained, which allows to calculate the value of microbial contamination of the air, depending on the distance to the road and number of vehicles. In the case of high levels of the microbiological monitoring of the basin air it’s necessary to carry out measures to reduce microbial contamination of the air, for example, regular watering roads, tree planting, vegetative barriers adsorbing pollutants, chemical treatment of disinfectants. The calculation of microbial contamination of the air near a residential building located at a distance of 10 meters from the highway in the central region of Volgograd is conducted using proposed in function prediction of microbial contamination. The developed technique allows us to make calculations without setting up experiments in a specialized microbiology laboratory.
Keywords: monitoring , microbial contamination of air , the regression model , mathematical modeling
Consider the choice of coating anodes for electrolysis of sodium hypochlorite nizkokontsentrovannogo 3% solution of sodium salt of food and water of the Black Sea. Defined corrosion resistance of anodes with different laying oxides of ruthenium and iridium and their characteristics: yield chlorine-current voltage on the cell growth dynamics of the concentration of active chlorine in the solution.
Keywords: oxide coatings, iridium, ruthenium, low concentration of sodium hypochlorite, the corrosion resistance of anodes according to the output current of chlorine, the electrolysis of a 3% solution of sodium edible salt and sea water.
The paper presents and analyzes the main methods of material stimulation of engineers and technician staff on russian and partly foreign enterprises, taking into account national management models. The article highlights the indicators that affect the stimulating part of remuneration for different occasions.
Keywords: engineering and technical personnel, remuneration, the stimulating part of remuneration, performance labor.
This article describes the way of the grain material in grain cleaning unit at various purification schemes. Researches on wheat injury when variii various schemes. Spotted seed purification scheme with the lowest percentage of damaged seeds and basic characteristics agaregata functioning under the scheme.
Keywords: grain material, fractionation, seed cleaning, grain cleaning machine
The composite cathode material of the core@shell type with the LiMn2O4@LiCoO2 formula of has been successfully synthesized using the solid-state reactions in several stages. Its structure has been studied by means of X-ray diffraction, scanning and transmission electron microscopy and vibrational infrared spectroscopy. Electrochemical investigation in two-electrode cell has been showed improvement of characteristics of the synthesized cathode material than the constituent components. The specific power of LiMn2O4@LiCoO2 is 650 mWh/g, against 450 and 500 mWh/g for LiCoO2 and LiMn2O4, respectively.
Keywords: lithium-ion batteries, cathode materials, Delafosse, X-ray structural analysis, electron microscopy, electrochemical properties
Problem research of display the orthogonal projection of four dimensional hypersurface defined by the equation in an implicit form one and two hyperplane. To communicate and bypass hypersurface Discriminants assumes that the hypersurface of the two-parameter family of two-dimensional display received surfaces in five-dimensional space. The analysis of kriminant four dimensional hypersurface orthogonal projection onto the coordinate hyperplane in two coordinate axes. The intersection of three dimensional hypersurfaces axiom (kriminant) defines a two-dimensional surface that is the envelope of the two-parameter family of two-dimensional surfaces. Are the necessary and sufficient conditions of existence of this envelope.
The results obtained are used to study the Discriminants four-dimensional hypersurface, the display of two-parameter family of spheres in a five-dimensional space.
Keywords: a family of surfaces, hypersurface, envelope, the display features, а discriminant.
The properties of the water-soluble high-modulus silicate systems: based on alkali metal polysilicates called liquid glass and chain their transformation from lower to higher oligomers, with the subsequent formation of colloidal solutions - silica sol. The methods of preparation, properties and applications of water-soluble high-modulus silicate systems. The possibilities of their use as a binder and modifying agents for various nanostructured composite materials. The examples of promising areas of application of liquid glass and high modulus of aqueous solutions of silicates in construction and industry. In particular show the possibility of using liquid glass and aqueous solutions of silicates in the production of nanostructured silicate polymer. In space engineering for manufacturing water-destructed mandrels used in the manufacture of solid rocket motor casings and pressure vessels 'cocoon' of composite materials by winding. The application of the inorganic sol to obtain a nanocomposite ceramics and monolithic blocks of silicon oxide, which can be used in various fields of modern technology. The possibility of using silica sol as a binder for refractory ultra-lightweight shielding materials used to protect equipment from high impacts. The directions of development of the production of new acid-resistant materials and linings for protection of chemical equipment, parts and components operating in corrosive environments.
Keywords: Keywords: water glass, silicate polymer concrete, additives, silicates organic bases tetrafurfuriloksisilan, furfural alcohol, nanostructure composite materials, water-soluble silicates, silica sol, sol-gel transition, cured xerogel water-destructed mandr
The paper contains a description of a new method for automatic generation of maps of goods placement. Map of goods placement created by the author's search algorithm. The algorithm is based on ideas of evolutionary search. The proposed algorithm works with a population of constant size, allows not use complex search methods and for a reasonable time find a solution close to the optimum.
Keywords: simulation, evolutionary computation, multicriteria optimization, genetic algorithms
The solid solution of LiMn1/3Cr1/3Fe1/3O2 with the structure of α-NaFeO2 isostructural with the widely used LiCoO2 has been synthesized and investigated as a cathode material. Rated voltage of LiMn1/3Cr1/3Fe1/3O2 relative to the lithium is 4 V. The possibility of charging − discharging the material to a specific capacity of 220-250 mAh/g at currents of C/15-C/50 without phase transformations has been experimentally demonstrated.
Keywords: lithium-ion batteries, cathode materials, Delafosse, solid solution, X-ray structural analysis, electrochemical properties
The results of calculations on the stability of slope lands treated in a new way. Device intrasoil walls combined with loosened intervals allows prevent subsurface runoff water, which reduces surface erosion slopes, improves the fertility of farmland returns a highly eroded areas in turn, eliminates the wetlands at the foot of the slopes. Established that the stability of the treated soil layer on the slope ample.
Keywords: stability of sloping land, subsurface walls, soil subsurface runoff, soil erosion, wetlands, deep tillage, moisture saturation slope.
Based on the analysis of works of finnish experts shows that learning russian language with learning the finnish language as a foreign supports the development of bilingual identity and language readiness of students.
Keywords: russian, finnish, teaching.
The combination of the unique, abnormal properties shown by oxidic systems with structure of spinel on the basis of transitional elements chromites draws attention of researchers for many years. Some systems on the basis of transitional elements chromites (for example, nickel and copper chromites) have critical elements (multicritical points, lines of phase transitions of the second sort, etc.) on the phase chart. Near these elements of the phase chart materials possess unique chemical and physical properties. Therefore development methods of receiving and research of phase forming and properties in NIO-CoO-CuO-Cr2O3 system represent fundamental and practical interest for chemistry and technology of inorganic substances. In this work processes of spinel structure formation in system 0,6 NiCr2O4 – 0,2 CoCr2O4 – 0,2 CuCr2O4 from crystal chemistry positions are considered. Formation of two solid solutions on the basis of nickel (II) chromite – with structure of cubic spinel and with tetragonal distorted structure is established. The influence of cooperative Yahn-Teller effect on processes of a spinel forming and on stabilizing impact of chloride of potassium on process of education of two spinel solid solutions is suggested. Influence of a power factor of cation stabilization in knots of a crystal lattice as one of the important factor in reaction of spinel structure formation is considered.
Keywords: spinels, chromites of transitional elements, Jahn-Teller effect